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MDCAT Chemistry Chemical Bonding Test Online

Malik TahirLast Updated: May 24, 2025

Chemistry Chemical Bonding MCQS Online Test

MDCAT Chemistry Chemical Bonding Chapter Online Test

Total Questions:	187
Time Allowed:	60 Minutes
Total Marks:	187
How to Attempt Test:	Please choose the right Option in MCQ-type question.
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MDCAT Chemistry Chemical Bonding Test

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Page 1 of 8

Chemistry

1. Fluorine has an atomic number 9 and Chlorine has 17. Which one has the highest electron affinity?

Both are equal

Cannot be determined

2. In BrF₃ molecule, the lone pairs occupy equatorial positions to minimize

Lone pair – lone pair repulsion and lone pair – bond pair repulsion

Bond pair – bond pair repulsion only

Lone pair – lone pair repulsion only

Lone pair – bond pair repulsion only

3. Sodium chloride imparts a yellow colour to the Bunsen flame. This can be interpreted due to the

Low ionization energy of sodium

Sublimation of metallic sodium to give yellow vapour

Photosensitivity of sodium

Emission of excess energy absorbed as a radiation in the visible region

4. If the molecule of HCl were totally polar, the expected value of dipole moment is 6.12 D (Debye) but the experimental value of dipole moment was 1.03 D. Calculate the percentage ionic character.

Zero

5. Geometry of simple molecule having sp3 hybrid orbital is

Linear

Tetrahedral

Triangular

Square planner

6. Which of the following is a non-directional orbital

SP²

7. Bohr’s model atom is contradicted by

Quarternization of angular members

Plank’s quantum theory

Quarternization of energy of electrons

Heisenberg’s uncertainty principle

8. Which molecule is polar among the following?

Carbon tetrachloride

Ethane

Carbon dioxide

Methanol

9. If the radius of first Bohr orbit be ɜ₀, then the radius of third Bohr orbit would be

9 x ɜ₀

3 x ɜ₀

1/2 x ɜ₀

6 x ɜ₀

10. The value of e/m ratio of electron is:

1.7588 x 10²⁰

6.02 x 10²³

1.7588 x 10¹¹

9.1095 x 10¯³¹

11. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers l = 1 and l = 2 are respectively

12 and 4

16 and 4

16 and 5

12 and 5

12. Force responsible to hold atoms together in a compound is called

Bond

Attractive force

Interaction

All of above represent same entity

13. The number of significant figures in 0.00200 is

Three

One

Two

Five

14. Element having the smallest atomic radius among the following is

15. Which of the following molecules has no net dipole moment?

CCl₄

CH₃Cl

HCl

H₂O

16. Geometry of simple molecule having SP³ hybrid orbital is

Square planner

Tetrahedral

Triangular

Linear

17. Which of the following statements about positive ions is incorrect?

They are larger than the atoms from which they were formed

They are also known as cations

They are formed when electros are formed from atoms

They are smaller than the atoms from which they were formed

18. Which of the following contains both polar and non-polar bonds?

CH₄

NH₄Cl

HCN

H₂O₂

19. Molecular orbital picture of N₂ indicates

No unpaired electron

None of these

One unpaired electron

Two unpaired electron

20. In Millikan oil – drop experiment, the charges on several different oil drops were as: -5.92. – 4.44, -2.96, -8.88. The units are arbitrary. Choose the likely value of the electronic charge in these arbitrary units?

-2.22

-2.96

-1.11

-1.48

21. Inter molecular forces in solid hydrogen are

All of these

Covalent forces

Hydrogen bonds

Van der Waal forces or London dispersion forces

22. Which of the following is to isoelectronic with rest of three?

Na⁺

S¯²

Cl¯

K⁺

23. The bond order in NO is 2.5 while that is NO⁺ is 3. Which of the following statements is true for these two species?

Bond length in NO is greater than in NO⁺

Bond length in NO⁺ is greater than in NO

Bond length in NO⁺ is equal to that in NO

Bond length is unpredictable

24. Anti-bonding MO is formed by

Multiplication of atomic orbitals

Addition of atomic orbitals

None of these

Subtraction of atomic orbitals

25. Which of these molecules require more bond energy?

Nitrogen

Hydrogen

Oxygen

Page 2 of 8

26. According to VSEPR theory, the shape of the water molecule is

Distorted tetrahedral

Linear

Planar triangle

Octahedral

27. Which quantum number is sufficient to describe the electron is hydrogen atom?

28. Which of the following molecule has Ā bond

H₂O

C₃H₆

O₂

NH₃

29. When a double bond is formed between two atoms, one of the bonds is a sigma bond and the other is a pi bond. The pi bond is created by the overlap of……

p orbitals

sp² hybrid orbitals

s orbitals

sp³ hybrid orbitals

30. The atomic number of an element is 35. What is the total number of electrons present in all the p-orbitals of the ground state atom of that element?

31. Noble gases are most stable of all other elements because

They do not react with one another

They have high ionization energies

They have completely filled s and p orbitals

They are mono atomic gases

32. Which of the following is the correct electron – dot formula of CO₂?

33. A lone pair of electrons in an atom implies

A pair of valence electrons not involved in bonding

A pair of electrons

A pair of electrons involved in bonding

A pair of valence electrons

34. Which has the minimum bond angle?

CH₄

NH₃

H₂S

H₂O

35. The number of σ and π-bonds present in pent-4-en-l yne is

3, 10

9, 4

10, 3

4, 9

36. Select the arrangement of electromagnetic radiation which starts with the lowest energy and increases to the highest energy

Visible, ultraviolet, infrared, gamma rays

X – radiation, visible, infrared, microwave

Radio, visible, infrared, ultraviolet

Microwave, infrared, visible, ultraviolet

37. Effective magnetic moment of Sc³ ion is

5.92

1.73

2.83

38. Which of the following compounds can form hydrogen bond?

CHCl₃

H₂O

CH₄

NaCl

39. The total number of possible values of magnetic quantum number for the value of l = 3 is

40. The central atom in BrF₅ has _?_ bonding pairs of electrons and _?_ non-bonding pairs of electrons.

5….0

1….5

0….5

5….1

41. Along a period the atomic radii

First decreases then increases

Decreases

Constant

Increases

42. What happens to IP value if shielding effect is greater?

Greater

Remain same

Lesser

No effect

43. In a double bond connecting two atoms there is a sharing of

4 electrons

1 electron

2 electrons

6 electrons

44. The force which holds the atoms together to form a compound is known as

Van der Waal’s force

Chemical bond

London force

Dispersion force

45. Which of the following geometry is associated with the compound in which the central atom assumes sp³ d hybridization?

Trigonal bipyramidal

Pyramidal

Angular

Planar

46. The four quantum numbers of the valency electron of potassium are

4, 4, 0, ½

4, 0, 0, ½

4, 1, 1, ½

4, 1, 0, ½

47. The configuration 1s² 2s² 2p⁵ 3s¹ shows

Excited state of fluorine

Excited state of neon

Excited state of O¯₂

Ground state of fluorine atom

48. Which of the following is a non-directional orbital?

SP²

49. In the ground state, an element has 13 electrons in its M shell. The element is

Chromium

Copper

Nickel

Iron

50. A student subtracted 0.00055 from 10.2345678 and reported the result as 10.23401. But his friend told him that result was wrong. What is the correct result?

10.2340178

10.23

10.234017

10.234

Page 3 of 8

51. With increasing principle quantum number, the energy difference between adjacent energy levels in H atom

Decreases

Remains constant

Increases

Decreases for low value of Z and increases for higher value of Z

52. The electronegativity of elements in a period from left to right

First decreases then increases

First increases then decreases

Decreases

Increases

53. According to VESPR Model the geometry of molecule having 5 bond pair in outer most shell will be

Triangular

Trigonal bipyramidal

Square planner

Octahedral

54. Geometry of molecule will be pyramidal if the outer post shell of the central atom has

1 bond pair 3 lone pair

3 bond pair one lone pair

2 bond pair 2 lone pair

3 lone pair 1 bond pair

55. Find the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25

6.9 BM

4.9 BM

3.0 BM

5.9 BM

56. Pi bonds are produced by overlapping of

Hybrid and un hybrid orbitals

Hybrid orbitals

Un-hybrid orbitals

Atomic orbital and hybrid orbital

57. Which of the following has maximum e/m value for positive rays?

Helium

Hydrogen

Nitrogen

Oxygen

58. Bond angle in water is

109.5°

120°

107°

104.5°

59. The structure of ICl₂¯ is

Trigonal bipyramidal

Square planar

Trigonal

Octahedral

60. Maximum hydrogen bonds in water are,

61. The energy required to remove electron from an atom is called

E.A

Ea.

E.N

I.P

62. Which one shows high % age of the ionic character?

HCI

H2O

HBr

63. Which of the following orbitals have a dumb bell shape?

64. Choose the correct statement about 2nd ionization energy

It is equal to the 1st ionization energy

It is always greater than 1st ionization energy

It is always less than 1st ionization energy

It may be greater or less than the 1st ionization depending upon ht nature of the element

65. In OF₂, number of bond pairs and lone pairs of electrons are respectively

2, 6

2, 10

2, 8

2, 9

66. Which of the following is the best explanation that CO₂ is a non-polar molecule?

None

SP hybridization

Dipole moment is zero

Linear geometry

67. Which of the following is not absolute term of element?

Ionization energy

Electron affinity

Electronegativity

Atomic size

68. Colour of the glow produced in the discharge tube

Depends on the gas used in the discharge tube

Depends on the pressure in the discharge tube

Does not depend on the nature of the gas used in the discharge tube

69. Deflection of blue light is lesser than violet because

Blue has higher wavelength

Blue has more energy

Blue is darker colour

Blue is absorbed more easily

70. When 2 lone pair and 2 bond pair are around the central atom reduction in the bond angle is up to. (in degrees)

107.5

109.5

102

104.5

71. Elements with ________ first ionization energies and ________ electron affinities generally from cations. Choose the correct point

Low, positive or slightly negative

High, very negative

Low very negative

None of these

72. Molecular orbitals are filled according to

All these

Pauli’s exclusion principle

Hund’s rule

Aufbau principal

73. Atom with higher atomic number produces X-rays of

X-rays not produced

Gamma rays

Shorter wavelength

Larger wavelength

74. Which of the sub – atomic particles is not charged?

Neutron

All these

Proton

Electron

75. Choose the correct statement

As bonding molecular orbitals become more stable, anti-bonding molecular orbital become equally less stable

In molecular orbitals, the number of bonding electrons equals the number of anti-bonding electrons

Each bonding molecular orbital can accommodate only one electron

The molecular orbitals in a molecule equals twice the number of constituent atomic orbitals

Page 4 of 8

76. When 6d orbital is complete, the entering electron goes into

77. Keeping in view the bonding molecular orbitals, find the incorrect statement

Every electron in the bonding molecular orbital contributes to the attraction between atoms

Bonding molecular orbitals have low electron density between the two nuclei

Bonding molecular orbitals are formed when the electrons waves are undergo constructive interference

Bonding molecular possess less energy than atomic orbitals from which they are formed

78. The twelve enter most electrons in O₂ molecule are distributed according to MOT as under. Find the correct one.

8 in bonding molecular orbitals, 4 in anti-bonding molecular orbitals

9 in bonding molecular orbitals and 3 in anti-bonding molecular orbitals

12 in bonding molecular orbitals, and zero in anti-bonding molecular orbitals

10 in bonding molecular orbitals and 2 in anti-bonding molecular orbitals

79. The relative attraction of the nucleus for the electrons in a chemical bond is called

None of these

Ionization energy

Electro negativity

Electron affinity

80. The carbon atoms in calcium carbide are held by

2 covalent, one co-ordinate bond

Ionic bonds

2π and one σ bond

2 sigma bonds

81. Quantum umber values for 2p orbitals are

n = 2, l = 0

n = 2, l = 1

n = 1, l = 0

n = 1, l = 2

82. Nitrogen gas is chemically inert gas due to the reason that

Some of the electrons are also present in anti-bonding molecular orbitals

It has high electronegativity

It has high heat of dissociation

There is triple bond between nitrogen atoms which make the molecule quite stable

83. Which one of these is weakest?

Van der Waal’s forces

Covalent bond

Ionic bond

Metallic bond

84. Lateral overlapping expected in

Ionic bond

Ā-bonds

Metallic bond

O-bond

85. In acetylene molecule, the two carbon atoms are linked by

One sigma bond and two pi-bonds

Three sigma bonds

Two sigma bonds and one pi-bond

Three pi-bonds

86. By combining n atomic orbital, numbers of hybrid orbitals will be

Impossible to predict

2 n

3 n

87. Water (H₂O) is liquid while hydrogen sulphide (H₂O) is a gas because

Water has higher molecular weight

Water molecules associate through hydrogen bonding

Sulphure has high electronegativity than oxygen

Hydrogen sulphide is a weak acid

88. Energy of an atom in a compound is

No change

Impossible to predict

Lesser than individual

Higher than individual

89. According to VSPER theory, ammonia molecule has --------- shape

Triangular

Tetrahedral

Pyramidal

Trigonal

90. Formulation of chemical bond between atoms of elements is based on

Octet rule

Pauli exclusion principle

Electropositive character of elements

Electronegative character of elements

91. The shape of ClO₃ according to valence shell electron pair repulsion theory will be

Square planar

Tetrahedral

Pyramidal

Planar triangle

92. The nature of inter-particle forces in benzene is

Dipole-dipole interaction

H-bonding

Dispersion force

Ion-dipole interaction

93. A long a period E.N __________ from left to right

Increases

Constant

Decreases

Variable trend

94. Energy released or absorbed when electrons are added in atom is

Activation energy

Electron affinity

Electronegativity

Ionization potential

95. The shape of the molecule SF₂Cl₂ is

Tetrahedral

Cubic

Octahedral

Trigonal bipyramidal

96. 2nd orbit is away from nucleus for H-atom as compared to first orbit

4-times

2-times

3-times

6-times

97. Azimuthal quantum number of last electron of ₁₁Na is

98. Which of the bonds, shown by the ___________ has the greatest polarity?

H – SH

H – Cl

H – NH₂

H – OH

99. The spectrum of He is expected to be similar to that of

He⁺

Li⁺

100. How many molecular orbitals may be constructed from the valence shell orbitals of the constituent atoms in CH₄?

Page 5 of 8

101. The spectrum of helium is expected to be similar to that of

He⁺

Li⁺

102. Which of the following molecules does not have a net dipole moment?

BF₃

H₂O

NH₃

BrF₃

103. Which is not true with respect to cathode rays?

Can be deflected by magnetic fields

Charged particles

Move with speed as that of light

A stream of electrons

104. Which kinds of bonding can be found in a sample of H₂O(l)?

Hydrogen bonds only

Both polar covalent and hydrogen bonds

Nonpolar covalent bonds only

Ionic and nonpolar hydrogen bonds

105. Which one among the following does not have the hydrogen bond?

Water

Liquid NH3

Phenol

Liquid HCl

106. When two ice cubes are pressed over each other, they unite to form one cube. Which of the following forces is responsible to hold them together?

Covalent attraction

Van der Waal’s forces

Dipole interaction

Hydrogen bond formation

107. In which one of the following does the central atom not possess can octet in its outer shell?

H₂O

NH₃

BH₃

CH₄

108. The relative attraction of the nucleus for the electrons in a chemical bond is called

Ionization energy

None of these

Electron affinity

Electronegativity

109. Which hydrogen halide among the following has the highest percentage of ionic character?

HCl

HBr

110. Number of sigma bonds in P₄O₁₀ is

111. ____________ has their outermost shell complete in atomic form

Gun metals

Noble gases

Alkali metals

Coinage metals

112. Nuclear radiation is emitted by those elements whose

Nuclei are stable

Molecules are unstable

Nuclei are unstable

Molecules are stable

113. In CCl₄, the four valencies of carbon are directed towards the corners of a

Hexagon

Cube

Tetrahedron

Prism

114. According to MO theory, the species O⁺₂ possesses

Bond order of 2.5

Stability lower then O₂

Diamagnetic character

Three unpaired electrons

115. On sp3 hybridization

Four p-orbitals are involved

One s and 3 p-orbitals are involved

All p-orbitals are involved

One p-orbital is involved

116. A chemist poured juice on soil. Which idea may he have in his mind?

There may be a possibility of a chemical reaction

Lemon juice is dangerous for health

Water should be preferred over lemon Juice for drinking

There may not be a possibility of chemical reaction

117. The velocity of photon is

Depends on its source

Independent of its wavelength

Depends on its wavelength

Equal to square

118. Which of the following equation represents the 1^st ionization energy of Na?

119. In O2 each oxygen atom is hybridized

Sp2

Sp3

All

120. Hydrogen chloride molecule contains

Electrovalent bond

Co-ordinate bond

Double bond

Covalent bond

121. The ionization energy

Does not change in a period

Generally increases from left to right in a period

Increase from top to bottom in a group

Does not change in a group

122. The number of d-electrons retained in Fe²⁺ (At. No. of Fe = 26) ions is

123. 1 erg of energy corresponds to

6.02 x 10²³ J/mol

6.02 x 10¹⁶ J/mol

10¯⁷ J/mol

1 erg/mol

124. Ammonia has a net dipole moment while boron trifluoride has zero dipole moment because

Fluorides are more electronegative

Boron trifluoride is pyramidal in shape while NH₃ is planar

Fluorides is more electronegative

NH₃ is pyramidal in shape while BF₃ is planar

125. Bond order for N2 molecule is

Page 6 of 8

126. How many sigma and pi bonds are present in tetra cyano ethylene?

Eight σ and eight π

Nine σ and seven π

Nine σ and nine π

Five π and nine σ

127. If atomic numbers of nickel and copper are 28 and 29 respectively. Which of the following does the electronic configuration 1s² 2s² 2p⁶3s²3p⁶3d⁹ represent?

Cu⁺

Ni²⁺

Cu²⁺

128. Shape of CIO₃¯ is

Triangular planar

Triangular bipyramidal

Triangular pyramidal

Tetrahedral

129. The correct set of quantum numbers (n, l and m) respectively of the unpaired electron of chlorine atom is:

3, 2, 1

3, 1, 1

2, 1, 0

2, 1, 1

130. An oxygen atom has mass of

5.316 x 10¯²³ g

16g

5.316 x 10¯²³ g

2.657 x 10¯²³ g

131. Covalent compounds are soluble in

All solvents

Polar solvents

Concentrated acids

Non-polar solvents

132. When two hydrogen atoms approach to form a chemical bond

The attractive forces dominate the repulsive forces

They energy of atoms increases

The two atoms start ionization

The repulsive force dominate the attractive forces

133. The nature of positive rays depends upon

The nature of discharge tube

All of these

The nature of electrode

The nature of residual gas

134. Among the alkaline earth metals the element forming predominantly covalent compounds is

Calcium

135. The de-Broglie wavelength of a particle with mass 1 g and velocity 100 m/s is

6.65 x 10¯³⁵ m

6.63 x 10¯³⁴ m

6.63 x 10¯³⁵ m

6.63 x 10¯³³ m

136. Al become isoelectronic with Ne

By losing three electrons

By losing two electrons

By gaining three electrons

By gaining two electrons

137. The energy of the first electron in helium will be

-54.4 eV

Zero

-5.44 eV

-13.6 eV

138. XeF₄ has shape of

Tetrahedral

Trigonal bipyramidal

Sphere

Square planar

139. When potassium metal is exposed to violet light

Ejection of some potassium atoms occurs

There is no effect

Ejection of electrons takes place

The absorption of electrons takes place

140. The third line of the Balmer series, in the emission spectrum of the hydrogen atom, is due to the transition from the

Fourth Bohr orbit to the first Bohr orbit

Sixth Bohr orbit to the third Bohr orbit

Seventh Bohr orbit to the third Bohr orbit

Fifth Bohr orbit to the second Bohr orbit

141. The number and type of bonds between carbon atoms in calcium carbide are

Two sigma, one pi

One sigma, two pi

One sigma, one pi

Two sigma, two pi

142. Which of the following has the greatest covalent character?

NaCl

SiCl₄

AlCl₃

MgCl₂

143. An electron has principal quantum number 3. The number of its (i) subshells and (ii) orbitals would be respectively

2 and 5

3 and 5

3 and 9

3 and 7

144. Pick out the molecule which has zero dipole moment

BCl₃

SO₂

H₂O

NH₃

145. Which of the following has more unpaired d-electrons?

Zn⁺

Ni³⁺

Fe²⁺

Cu⁺

146. Which of the following would have a permanent dipole moment?

XeF₄

SF₄

SiF₄

BF₃

147. Which of the solid does not contain covalent bond

Graphite

Diamond

Ice

Copper

148. Which of the following has zero depolemoment?

CFCl₃

ClF

PCl₃

SiF₄

149. For principle quantum number, n = 4, the total number of orbitals having 1 = 3 is

150. Which of the following element’s outermost orbits last electron has magnetic quantum number m = 0?

Page 7 of 8

151. Which of the following is not isoelectronic?

Mg²⁺

Cl¯

O²¯

Na⁺

152. Unit of dipole moment is

Pascal

Poise

Newton

Debye

153. Fluorine molecule is formed by

The axial p-p overlap

The axial s-p overlap

The sidewise p-p overlap

The overlap of two sp² hybrid orbitals

154. The number of anti-bonding electron pairs in O₂²¯ molecular ion on the basis of MOT is

155. The electro negativities of F, Cl, Br and I are 4.0, 3.0, 2.8, 2.5 respectively. Hydrogen halide with a high percentage of ionic character is

HBr

HCl

156. Which of the following species is paramagnetic?

CN¯

CO₂

O²¯

157. In which of the following pairs, the numbers of electrons in the outermost shell are different?

Ge, Sn

Se, Te

As, Sb

In, Pt

158. H-bonding is not present in

Water

Glycerine

Hydrogen sulphide

Hydrogen fluoride

159. Which one of the following pairs of atoms is most likely to form an ionic bond?

Na and F

C and F

O and F

N and F

160. Which orbital of the following has a principal quantum number of 3 and an angular momentum quantum number of 27?

161. Which one of the following molecules shows high percentage of ionic character?

HCl

H₂O

HBr

162. Which of the following has unchanged valency?

Oxygen

163. The most suitable method of the separation of a mixture of ortho and para-nitrophenol mixed in the ratio of 1 : 1 is

Vaporization

Crystallization

Colour spectrum

Distillation

164. Number of π-bonds in naphthalene is

165. A molecule in which sp² hybrid orbitals are used by the central atom in forming covalent bonds is

N₂

SO₂

He₂

PCl₅

166. If the value of principal quantum number is 3, the total possible values for magnetic quantum number will be

167. Outermost shells of two elements X and Y have two and six electrons respectively. If they combine, the expected formula of compound will be

X₂Y

X₂Y₃

XY₂

168. The boiling point of heavy water is

110°C

101.4°C

99°C

108°C

169. Which of the following hydrides has the lowest boiling point?

H₂Te

H₂O

H₂S3

170. The shape of H₃O⁺ is

Triangular planar

Angular

Pyramidal

Tetrahedral

171. Ionic radius in a period from left to right

First increases then decreases

Increases

Decreases

First decreases then increases

172. Which carbon is more electronegative?

sp³-hybridized carbon

always same irrespective of its hybrid state

sp- hybridized carbon

sp²- hybridized carbon

173. Which of the following will have highest value of electron affinity

174. Electronic configuration of K is

[Kr]4S¹

[AR]4S²

[He]4S¹

[AR]4S¹

175. Which of the following phenomena will occur when two atoms of the elements having same spin of electron approach for bonding?

Bonding will not occur

Orbital overlap will not occur

None of these

Both A and B are correct

Page 8 of 8

176. Lewis acids are

No such acids exist

Octet is complete

Electron rich

Electron deficient

177. The energy of a photon is given as, ∆ E/atom = 3.03 x 10¯¹⁹ J atom¯¹ then, the wavelength (λ) of the photon is

6.56 nm

656 nm

65.6 nm

0.656 nm

178. The bond angle H – O – H in ice is closest to

120°

90°

109°

60°

179. Unit of dipole moment is

Debye

Newton

Pascal

Poise

180. Which of the following species has lone pair of electrons on central atom?

CH₄

Pcl₄

N⁺H₄

PCl₃

181. The relative attraction of the nucleus for the electrons in a chemical bond is called

Electro negativity

None of these

Ionization energy

Electron affinity

182. Which of the following value of Electronegativity difference corresponds the formation of Ionic Bond?

Lesser then 1.7

No specificity exist

Greater than 1.7

Equal to 1.7

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Malik TahirLast Updated: May 24, 2025

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