ECAT Chemistry Reaction Kinetics Test Online

1. Ammonium carbonate when heated to 200°C gives a mixture of NH₃ and CO₂ vapour with a density of 13.0. what is the degree of dissociation of ammonia carbonate?

2. For the reaction 2HI H₂ + I₂

3. 3 mole of reactant A and one mole of reactant B are mixed in a vessel of volume 1 liter. The reaction taking place is A + B ⇌ 2C. If 1.5 mol of C is formed at equilibrium, the value of Kc is

4. Effect of temperature on reaction rate is given by

5. H₂ + I₂ ⇌ 2HI Which one of the following will not affect the rate of this reaction?

6. The experimental relationship between a reaction rate and concentration of reactants is called

7. Which statement is incorrect for a buffer solution?

8. The rate of reaction between A and B increases by a factor of 100, when the concentration with respect to A is increased 10 folds, the order of reaction w.r.t. A is

9. The addition of a catalyst to a reaction

10. For the reaction PCl₅(g) ⇌ PCl₃(g) + Cl²(g) the forward reaction at constant temperature is favoured by

11. If the rate of reaction for 2A + B → Products is K [A]² [B] and A is present in large excess, then order of reaction is

12. 4.5 moles each of hydrogen and iodine heated in a sealed ten liter vessel. At equilibrium 3 moles of HI were found. The equilibrium constant for H₂(g) + I₂(g) ⇌ 2HI(g) is

13. When we increase the temperature, the rate of reaction increases because of

14. Temperature coefficient of a reaction is 2. When temperature is increased form 30°C to 100°C, rate of the reaction increases by

15. At 500 K the equilibrium constant for reaction cis-C₂H₂Cl₂ ⇌ trnas-C₂H₂Cl₂ is 0.6. At the same temperature, the equilibrium constant for the reaction trans- C₂H₂Cl₂ ⇌ cis- C₂H₂Cl₂ will be

16. Of the following, which change will shift the reaction towards the product? I₂(g) ⇌ 2I(g) ∆H°t(298 K) = + 150 kJ

17. Hydrogen gas and iodine vapours combine to form HI at 425°C. The same composition of mixture is present if we start with decomposition of HI. It suggests

18. Which of the solution among the following has highest pH?

19. In the equilibrium N₂ + 3H₂ ⇌ 2NH₃ + 22 kcal the formation of ammonia is favoured by

20. In a reaction A + 2B ⇌ 2C, 2.0 moles of ‘A’ 3 moles of ‘B’ and 2.0 moles of ‘C’ are placed in a 2.0 L flask and the equilibrium concentration of ‘C’ is 0.5 mol/L. The equilibrium constant (K) for the reaction is

21. A reactions 50% complete is 2 hours and 75% complete in 4 hours order reaction is

22. The hydrolysis of ester in alkaline medium is a

23. Which statement about the following equilibrium is correct? 2SO₂(g) + O₂(g) → 2SO₃(g) ∆H = -188.3 kJmol¯³

24. Large the surface area of the reactant molecules

25. The average rate and instantaneous rate of a reaction are equal

26. Reaction with high activation energy

27. If the rate of the reaction is equal to the rate constant, the order of reaction is

28. With increase in 10°C temperature, the rate of reaction doubles. This increase in rate of reaction is due to

29. The rate of a reaction that does not involve gases, does not depend upon

30. A chemical reaction is catalyzed by X. Hence X

31. The rate of reaction determined at given time is called

32. A chemical reaction is in equilibrium when

33. Which of the following is the property of inhibitors?

34. Which of the following statement about the catalyst is/are true?

35. A solution with pH = 0, its H⁺ ion concentration is

36. Under a given set of experimental condition, with increase in the concentration of the reactants the rate of

37. Pure H₂O has H₃O⁺ ion concentration of 10¯⁶ mole dm¯³ at 90°C is

38. Collision theory is application to

39. The activation energy for a reaction is 90 keal mol¯¹ the approximate increase in rate constant, when it’s temp is increased from 300K to 310K is

40. The rate at which a substance reacts depends on its

41. The time taken for 90% of a first order reaction to complete is approximately

42. The enzyme which can catalyst the conversion of glucose to ethanol is

43. The half period of ₆C¹⁴ is 5760 years, 100 mg of sample will be reduced to 25 mg in

44. The rate of reaction is doubled for 10°C rise in temperature. The increase in the reaction rate as a result of temperature rise from 10°C to 100°C is

45. The addition of a catalyst to the reaction system

46. For a reaction if Kp > Kc, the forward reaction is favoured by (T > 15 K)

47. The rate of an irreversible reaction

48. The effect of increasing the pressure of the following equilibrium 2A + 3B ⇌ 3A + 2B is

49. RCOOR + H₂O HIC→ RCOOH + R’OH. What type of reaction is this?

50. When the rate of reaction is entirely independent of the concentration of reactant molecules then order of reaction is

51. An example of autocatalytic reaction is

52. 1 mole of N₂ and 2 moles of H₂ are allowed to react in a 1 dm³ vessel. At equilibrium 0.8 mole of NH₃ is formed. The concentration of H₂ in the vessel is

53. When a reaction proceeds in a sequence of steps, the overall rate is determined by

54. When KCIO₃ is heated, it decomposes into KCI and O₂. If some MnO₂ is added, the reaction goes much faster because

55. Which of the following statement regarding catalyst is not true?

56. If the rate of reaction for 2A + B → Products is K [A]² [B] and A is present in large excess, then order of reaction is

57. Choose the incorrect statement from the following

58. 75% of a first order reaction was completed in 32 minutes. When was 50% of the reaction completed?

59. In the reaction N₂(g) + O₂(g) ⇌ 2NO(g) ∆H = + 180.7 kJ. One increasing the temperature the production of NO

60. The gaseous reaction A + B ⇌ 2C + D q most favoured at:

61. A reaction A → B follows a second order kinetics. Doubling the concentration of A will increase the rate of formation of B by a factor or

62. Which of the following is a characteristic of a reversible reaction?

63. If NH₃ gas is dissolved in H₂O, PH of the solution

64. The unit of ionic product of H₂O is

65. When NH₃ is added to pure H₂O than concentration of any one of the following species is decreased

66. For a given reaction t₁/2 = 1/ka. The order of reaction is

67. The rate of reaction

68. For a chemical reaction ______ can never be a fraction

69. In equation, CHCI₃ + CI₂ → CCI₄ + HCI, the rate = k [CHCI₃][CI₂]½ the order of reaction is,

70. Oxidation of oxalic acid by acidified KMnO₄ is an example of autocatalysis, it is due to which of the following?

71. A zero order reaction is one whose rate is independent of

72. According to Le-Chatelier’s principal, adding heat to a solid and liquid in equilibrium will cause the

73. The reaction, 2SO₂(g) + O₂(g) → 2SO₃(g) is carried out in a 1 dm³ vessel and 2 dm³ vessel separately. The ratio of the reaction velocities will be

74. The reaction 2H₂O₂ → 2H₂O + O₂ is, r = k [H₂O₂]

75. Give t₁/2 = 3 hr, then how many gram of a substance will remain after 18th hr from 300 gram of s substance

76. The phenomenon of emission of visible light as result of chemical change is known as

77. The half-life period for a first order reaction is 693 seconds. The rate constant of this reaction would be:

78. 75% of first order reaction is complete in 30 minutes. What is the time required for 93.75% of the reaction (in minutes)?

79. The concentration of reactants is increased by x, then equilibrium constant K becomes

80. 4 moles of A re mixed with 4 moles of B, when 2 moles of C are formed at equilibrium according to the reaction A + B ⇌ C + D The value of equilibrium constant is

81. For a reaction A + B ⇌ C + D the partial presseres of A, B, C and D are 0.5, 1.00, 0.05 and 10 atm respectively at equilibrium. The value of kP for this reaction is

82. Choose the incorrect statement from the followings

83. In a first order reaction, the concentration of the reactant, decreases from 0.8 M to 0.4 M in 15 minutes. The time taken for the concentration to change from 0.1 M to 0.025 M is

84. Which one of the following is a buffer solution?

85. The rate of a reaction can be increased in general by all the factors except by

86. In a reaction A + B ⇌ C + D, the initial concentration of A and B were 0.9 mol dm¯³ each. At equilibrium the concentration of D was found to be 0.6 mol dm¯³. What is the value of equilibrium constant for the reaction?

87. A catalyst increases rate of reaction by

88. 1 mole of hydrogen and 2 moles of iodine are taken initially in a 2 liter vessel. The number of moles of hydrogen at equilibrium is 0.2. Then the number of moles of iodine and hydrogen iodide at equilibrium are

89. For most of the chemical reactions the rate of reaction

90. The rate of reaction A + B → Products is given by the equation r = k [A][B] If B is taken in large excess, the order of the reaction would be

91. The value of Kp is greater than Kc for a gascous reaction when

92. The activation energy of a reaction can be determined by

93. Initially the rate to increase in concentration of products in a reaction is

94. One the basis of Le-Chatelier’s principle, predict which of the following conditions would be unfavourable for the formation of SO₃? Given that 2SO₂ + O₂ ⇌ 2SO₃; ∆H = -42 kcal

95. Which of the following will not change the concentration of ammonia in the equilibrium N₂(g) + 3H₂(g) ⇌ 2NH₃(g); ∆H = -x kJ

96. A scientist prepared compound in laboratory. He found that is has two forms. One amorphous from A and another crystalline from C., Both A and C reacts with sulphuric acid. One possible prediction is that

97. Rate of a chemical reaction can be kept constant by

98. An excess of aqeous AgNO₃ is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ions in the filtrate

99. The active mass of 64 g of HI in a two liter flask would be

100. The PH of 10¯³ mol dm¯³ of aqueous solution of H₂SO₄ is

101. The equilibrium constant Kᵨ for the reaction PCl₅(g) ⇌ PCl₃(g) + CI₂(g) is 16. If the volume of the container is reduced to half of its original volume, the value of Kᵨ for the reaction at the same temperature will be

102. A catalyst can be deactivated by the presence of even a small amount of impurity. This is called

103. Large the surface area or the reactant molecules

104. Agcl dissolved with concentration (Z x 10¯²) Ksp will be

105. The mathematical reaction between the rate of reaction and the concentration of reactants is called x

106. 1.1 mol of A is mixed with 2.2 mol of B and the mixture is kept in one liter flask till the equilibrium is reached. At equilibrium, 0.2 mol of C is formed. If the equilibrium reaction is A + 2B 2C + D, the value of equilibrium constant is

107. An increase in concentration of reactants

108. Rate expression for NH³ synthesis is

109. In a reversible reaction, two substance are in equilibrium. If the concentration of each one is reduced to half, the equilibrium constant will be

110. The dimension of rate constant of a second order reaction involves

111. The chemical method used for determination of the rate of reaction is

112. A student started to work on 100g of a compound whose half – life is 5 hours, how much compound is left after 25 hours

113. A substance ‘A’ decomposes in solution following the first order kinetics. Flask I contains 1 L of 1 M solution of A and flask II contains 100 ml of 0.6 M solution. After 8 hr the concentration of A in flask 1 become 0.25 M, what will be the time for concentration of A is flask II to become 0.3 M

114. For a chemical reaction A → B, it is found that the rate of reaction doubles when the concentration of A is increased four times. The order in A for this reaction is

115. The unit of rate constant for a zero order reaction is

116. The rate of reaction

117. According to Law of Mass Action, rate of a chemical reaction is proportional to

118. Half-life period of 2nd order reaction is

119. The expression k = A ͤ Ea/RT is refered as

120. The half-life of a reaction is halved as the initial concentration of the reaction is doubled. The order of the reaction is

121. The rate of reaction

122. Factor which slows down the rate of reaction is

123. One mole of compound AB reacts with one mole of a compound CD according to the equation AB(g) + CD(g) ⇌ AD(g) + CB(g). When equilibrium had been established it was found that ¾ mole each of reactants AB and CD had been converted to AD and CB. There is no change in volume. The equilibrium constant for the reaction is

124. The rate constant of a reaction at temperature 200 K is 10 times less than the rate constant at 400 K. What is the activation energy (Eₐ) of the reaction?(R = gas constant)

125. In a lime kiln, to get higher yield of CO₂, the measure that can be taken is:

126. Which statement is incorrect about the catalyst?

127. Which statement is not correct?

128. The value of Kp is greater than Kc for a gaseous reaction when

129. A first order reaction is 75% complete after 32 minutes. When was 50% of the reaction completed?

130. All of the following are the postulates of Arrhenius theory of ionization except

131. If initial concentration of reactants in certain reaction if doubled, the half-life period of the reaction doubles, the order of a reaction is

132. The compounds A and B are mixed in equimolar proportion to form the products, A + B ⇌ C + D. At equilibrium, one third of A and B are consumed. The equilibrium constant for the reaction is

133. The half-lives of 2 samples are 0.1 and 0.4 seconds. Their initial conc. Are 200 and 50 respectively? What is is the order of the reaction?

134. The rate of chemical reaction depends on the nature of reactants because

135. Which is correct about zero order reaction?

136. A reaction involving two different reactants can never be

137. A gas bulb is filled with NO₂ gas and immersed in an ice bath at 0°C which becomes colourless after sometime. This colourless gas will be

138. The amount of ₅₃I¹²⁸, (I₃₆ = 25 min) left after 50 min is

139. For a reaction of type A + B → products it is observed that doubling concentration of A causes the reaction rate to be four times a great, but doubling amount of B does not affect the rate. The rate equation is

140. Rate constant is case of first order reaction is

141. Instantaneous rate of a chemical reaction is

142. 1 dm³ of 2 M CH₃COOH is mixed with 1 dm³ of 3 M ethanol to form ester. The decrease in the initial rate if each solution is diluted with an equal volume of water would be

143. The ionic product of solution is greater than solubility product. The solution is

144. The pH of buffer solution is 4.74. On adding 0.1 ml (0.00001M) HCl solution, the pH of solution will be

145. The strongest base among the following is

146. Rancidity produced in butter can be decreased by adding Quinoline to the butter. The statement shows that

147. For a first order reaction, the half-life period is independent of

148. The number if atoms or molecules whose concentration determines the rate of a chemical reaction is called

149. The rate of a first order reaction is 1.5 x 10¯² mol L¯¹ at 0.5 M concentration of the reactant. The half-life of the reaction is

150. Which of the following favours the reverse reaction in chemical equilibrium?

151. Units of rate constant for the first and zero order reactions in terms of molarity, M units are respectively

152. Rate of 1st order depends upon

153. The rate of forward reaction is two times that of the reverse reaction at a given temperature and identical concentration, K equilibrium is

154. You store food in a fridge to prevent spoilage. Which factor are you applying to slow the rate of reaction?

155. A substance which retards the rate of reaction is called

156. The firs order rate constant of decomposition of N₂S₅ is 6.2 x 10¯⁴ sec. The initial pressure is 290 mm Hg and final is 360 mmHg. t/2 is

157. Which property of liquid is measured by polarimeter?

158. In zero order reaction, the rate in independent of

159. What is the time required for a first order reaction to be 99% complete, compared to the time taken for the reaction to be 90% complete?

160. 0.1 M HCl has pH = 1..1, it is about 100 times stronger acid, pH of acetic acid is

161. 0.1 M HCl has pH = 1.0, it is about 100 times stronger than acetic acid. Then pH of acetic will be

162. Which types of metals are usually used as catalyst?

163. The dimensions of rate of reaction are

164. Which of the following will not change the concentration of ammonia at the equilibrium?

165. The rate of reaction between two specific time intervals is called